WATCH: Shocked George Clooney finds out on camera about Brad...

George Clooney just couldn't believe it.

>> Angelina Jolie files for divorce from Brad Pitt

On Tuesday, news that Angelina Jolie filed for divorce from her husband of two years, Brad Pitt, rocked the entertainment world, shocking fans.

>> Jennifer Aniston jokes invade Twitter following Jolie, Pitt divorce news

Perhaps the most surprised was Pitt’s good friend, George Clooney, who heard of the news during a taped interview.

>> Trailer for Brad Pitt’s new movie released amid divorce revelation

“What happened?” Clooney said, obviously surprised. “I didn’t know that. I feel very sorry then. That’s a sad story and unfortunate for a family. It’s an unfortunate story about a family. I feel very sorry to hear that.”

>> PHOTOS: Angelina Jolie, Brad Pitt through the years

He added, “This is the first I’ve heard of it.”

>> Watch the video here

(H/T: PEOPLE)

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